Typical background concentrations. Odor threshold – rotten egg smell. Permissible Exposure Level – 8 Hours. Possible fatigue, loss of appetite, headache, irritability, poor memory, dizziness. Intense odor. Above 30ppm odor is sweet or sickeningly sweet. Mild Irritation - eyes, throat – 1 Hour. Coughing, eye irritation, loss of smell 2-15 minute.