Unraveling fundamental active units in carbon nitride for ...
2021年1月12日 · Herein, we clarify the fundamental active units in CN for photocatalytic oxidation reactions through the construction of CN with more defined molecular structures.
Mechanistic insight into reaction behaviors of acetonitrile catalytic ...
2023年9月5日 · And further mechanism research by DRIFTS concluded that CH 3 CN degradation to N 2 on Cu/SBA-15 catalyst mainly followed oxidation pathway reaction via isocyanide (NCO) intermediate.
Cu Anchored Carbon Nitride (Cu/CN) Catalyzes Selective Oxidation …
2024年11月27日 · In this study, we introduce copper atoms into carbon nitride (Cu/CN), facilitating the generation of hydroperoxyl radicals (·OOH) as primary reactive oxidants and offering reaction conditions entirely devoid of H 2 O 2 via the Fenton reaction. Cu/CN demonstrates selective oxidation of thiols to disulfides, in contrast to other current ...
Nickel ferrocyanide as a high-performance urea oxidation ... - Nature
2021年9月20日 · Here we demonstrate that a nickel ferrocyanide (Ni2Fe(CN)6) catalyst supported on Ni foam can drive the urea oxidation reaction with a higher activity and better stability than those of ...
Electrochemical oxidation of ferricyanide | Scientific Reports
2021年11月29日 · We report the electrochemical oxidation of ferricyanide, [FeIII(CN)6]3− and characterised the oxidation product by in-situ FTIR and XAS spectroelectrochemistry methods.
Making Carboxylic Acids by the Hydrolysis of Nitriles
2023年1月23日 · Nitriles are produced in two important reactions - both of which result in an increase in the length of the carbon chain because of the extra carbon in the -CN group. They are formed in the reaction between halogenoalkanes (haloalkanes or alkyl halides) and cyanide ions.
Amide synthesis by C-N coupling, hydrolysis, oxidation
In an unusual oxidative coupling reaction of isocyanide and toluene derivatives using tetrabutylammonium iodide (TBAI) as a catalyst, the isocyano group acts formally as an N1 synthon, thus expanding the reactivity profile of isocyanides.
A rational construction of Pt@Cu-ZSM-5@CuOx catalyst with …
2023年5月1日 · Cerium-copper oxides prepared by solution combustion synthesis for total oxidation reactions: from powder catalysts to structured reactors
Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions
2016年9月30日 · Pd-catalyzed cross-coupling reactions that form C–N bonds have become useful methods to synthesize anilines and aniline derivatives, an important class of compounds throughout chemical research. A ...
The Mechanism of Acid-Catalyzed Nitrile Hydrolysis
Need some good practice on the reactions of carboxylic acids and their derivatives? Check this 45-question, Multiple-Choice Quiz with a 50-min Video Solution covering the reactions of acids, esters, lactones, amides, acid chlorides and etc.