Aryl group - Wikipedia
Arylation is the process in which an aryl group is attached to a substituent. It is typically achieved by cross-coupling reactions. The simplest aryl group is phenyl, which is made up of a benzene …
Direct arylation of strong aliphatic C–H bonds | Nature
2018年8月1日 · Here we describe a protocol for the direct C (sp3) arylation of a diverse set of aliphatic, C–H bond-containing organic frameworks through the combination of light-driven,...
Arylation - an overview | ScienceDirect Topics
Arylation is a chemoselective process that allows for selective attack at the amide nitrogen while avoiding disubstitution, even in the presence of a free aniline group. It is a mild and versatile …
Palladium-catalyzed α-arylation for the addition of small rings to ...
2019年9月9日 · We report a generally applicable approach to attach small rings to a wide range of aromatic compounds by palladium-catalyzed α-arylation of cyclopropyl, cyclobutyl and …
Arylation Chemistry for Bioconjugation - PMC
Arylation reactions are desired for natural amino acid residues other than lysine and cysteine. Targeting other nitrogen- and oxygen-based nucleophiles (e.g., residues of His, Ser, Thr, and …
The direct arylation of allylic sp3 C–H bonds via organic and ...
2015年3月4日 · Here we report the use of both photoredox and organic catalysis to accomplish a mild, broadly effective direct allylic C–H arylation. This C–C bond forming reaction readily …
Arylation - an overview | ScienceDirect Topics
Direct (hetero) arylation is a sustainable, atom-economic and environmentally benign synthetic protocol. Recent advances in direct arylation for preparing high performance conjugated small …
Electrochemical Arylation Reaction | Chemical Reviews - ACS …
2018年7月2日 · The electrochemical arylation of nitrogen-containing compounds can be a key step for the formation on N-heterocyclic derivatives. A convenient method for the …
Electrochemical Arylation of Aldehydes, Ketones, and Alcohols: …
2020年12月29日 · Despite great progress, there is still a great gap to develop an ideal arylation method featuring mild conditions, good functional group tolerance, and readily available …
Meerwein arylation - Wikipedia
The Meerwein arylation is an organic reaction involving the addition of an aryl diazonium salt (ArN 2 X) to an electron-poor alkene usually supported by a metal salt. [1] The reaction product is …